Our sources disagree on where Rio Real is governed from. If you know it, tell us with a source.
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Boundaries: Instituto Brasileiro de Geografia e Estatística (IBGE), OCHA ROLAC (https://data.humdata.org/dataset/brazil-administrative-level-0-boundaries) via geoBoundaries, CC BY 3.0 IGO (https://creativecommons.org/licenses/by/3.0/igo/); boundaries modified
Nothing has been written about Rio Real here, and neither Wikipedia nor Wikivoyage has an article we could draw one from. If you know the place, that makes you a better source than anything we have. Tell us what is worth knowing and where you got it.
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